4-chloro-3,5-dioxaphosphacyclohepta[2,1-;3,4-']dinaphthalene (binol-pcl) as a bulky and efficient reagent for the transformation of symmetric and asymmetric benzoins to corresponding benziles

Authors

nader noroozi pesyan

department of chemistry, faculty of science, urmia university, 57159, urmia, iran mahnaz saraei

department of chemistry, tabriz payam-e-noor university, tabriz, iran bakhshali massoumi

department of chemistry, tabriz payam-e-noor university, tabriz, iran maryam sarbazi

department of chemistry, tabriz payam-e-noor university, tabriz, iran

abstract

4-chloro-3,5-dioxaphosphacyclohepta[2,1-;3,4-']dinaphthalene (binol-pcl) was found to be an efficient, bulky and selective reagent for the transformation of symmetric and asymmetric benzoins to the corresponding benziles at 0 °c to room temperature under nitrogen atmosphere in good yield.

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4-Chloro-3,5-dioxaphosphacyclohepta[2,1-;3,4-']dinaphthalene (BINOL-PCl) as a Bulky and Efficient Reagent for the Transformation of Symmetric and Asymmetric Benzoins to Corresponding Benziles

4-Chloro-3,5-dioxaphosphacyclohepta[2,1-;3,4-']dinaphthalene (BINOL-PCl) was found to be an efficient, bulky and selective reagent for the transformation of symmetric and asymmetric benzoins to the corresponding benziles at 0 °C to room temperature under nitrogen atmosphere in good yield.

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Journal title:
journal of the iranian chemical research

جلد ۴، شماره ۱، صفحات ۵۱-۵۷

Keywords
[ 4 , ' c h l o r o ' , 3 , 5 , ' d i o x a p h o s p h a c y c l o h e p t a [ 2 ' , 1 , ' u f 0 6 1 ' , 3 , 4 , ' u f 0 6 1 & a p o s ; ' , ' ] d i n a p h t h a l e n e ' , ' t r a n s f o r m a t i o n r e a g e n t ' , ' b e n z o i n ' , ' b e n z i l ' ]

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